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Don't step on his foot, you will pain him.

to cause physical or emotional discomfort or suffering to someone.
The injury will pain him for weeks.
His words did not pain her.
Loud noises pain my ears.
pain someone deeply
pain someone greatly
pain someone's feelings
hurt
ache
afflict
I have a sharp pain in my leg after the accident.

A physical sensation of discomfort or distress, often caused by injury or illness.
The pain was intense.
He felt a dull pain.
She ignored the pain.
sharp pain
mild pain
constant pain
ache
hurt
discomfort